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KlementineJBS / USYD_PhD_ELN

This repository forms the electronic laboratory notebook (ELN)for Klementine Burrell-Sander's PhD's
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KBS41-2 - NBS reaction on KBS36 (3 g scale) #132

Closed KlementineJBS closed 10 months ago

KlementineJBS commented 10 months ago

Link to HIRAC.

HIRAC NBS reaction Breaking Good.docx

Previous attempt was #124

Reaction scheme

KBS41 - NBS reaction on KBS36

Outcome

3.2782 g (3016.7 g of product, conversion rate of 92%, yield of 77%)

KlementineJBS commented 10 months ago

27.08.23

  1. SM (2.778 g, 14.1 mmol) in MeCN
  2. added tosic acid (3.6373 g, 21.1 mmol, 1.5 equiv.) and NBS (3.0769 g, 16.92 mmol)

Vial: 15.7087 Full vial: 18.9869 Mass: 3.2782 g (3016.7 g of product, conversion rate of 92%, yield of 77%)

KlementineJBS commented 10 months ago

H NMR

KBS41-2 cr.pdf KBS41-2 cr_1.zip