KlementineJBS / USYD_PhD_ELN

This repository forms the electronic laboratory notebook (ELN)for Klementine Burrell-Sander's PhD's

2 stars 0 forks source link

Closed KlementineJBS closed 1 month ago

KlementineJBS commented 9 months ago

Link to HIRAC.

Reaction scheme

KBS28 alternative - Click coupling of 1-azidonaphthalene and propargyl alcohol

KlementineJBS commented 9 months ago

Identifier	Link	Yield (%)	Cu source	Further info
1	#53	46	copper sulfate	-
2	#55	67	copper sulfate	heated, excess propargyl alcohol, 40 hrs reaction time
3	#60	53	copper sulfate	24 hrs reaction time
4	#147	81	copper iodide	40 hrs
5	#150	32	copper iodide	22 hrs
6	#151	73	copper iodide	6 days
7	#153	89	copper iodide	5 days
8	#161	94	copper iodide	2 days
9	#182	66	copper iodide	24 hrs

KlementineJBS commented 9 months ago

KBS28-2 F28-33.1.zip KBS28-2.pdf (only F28-33 contains clean sample)

Peaks at 226.15 [M+H]+ and 248.14 [M+Na]+ - in agreement with previous attempts.

Original data file can be found in the code section.

high res pos ESI, found [M+Na]+, error = 0.93 ppm

KlementineJBS commented 8 months ago

Note that product is a red-brown solid.