literature evidence of solvent viscosity effect in microgel system

[marcocaggioni]

found this article https://www.mdpi.com/2311-5521/4/1/3/pdf

showing this figure:

their point is:

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and also this one:

https://pubs.rsc.org/en/content/articlepdf/2020/sm/d0sm01196g

they have flow curve in glycerin, peg, and water

when they make a mastercurve the result is:

[marcocaggioni]

G_PG_P_flow_curves.csv

I digitized the data in the figure from this article: https://pubs.rsc.org/en/content/articlepdf/2020/sm/d0sm01196g - figure 9

G_2pcCP		G_1p5pcCP	G_1pcCP		PG_2pcCP	PG_1p5pcCP	PG_1pcCP	P_2pcCP		P_1p5pcCP
X	Y	X	Y	X	Y	X	Y	X	Y	X	Y	X	Y	X	Y
0.001104	19.63041	0.000762	4.862602	0.000501	1.097499	0.00116	14.17474	0.001189	3.67838	0.000501	0.359381	0.001	5.59081	0.000595	0.453488
0.001312	19.63041	0.001051	4.862602	0.00061	1.204504	0.00156	14.17474	0.001522	3.853529	0.000657	0.394421	0.00125	5.59081	0.000762	0.497702
0.001639	20.56512	0.001345	5.336699	0.000743	1.204504	0.001997	15.55676	0.001948	4.037017	0.000906	0.432876	0.001562	5.857021	0.001025	0.521401
0.002047	20.56512	0.001722	5.857021	0.001	1.204504	0.002686	15.55676	0.002434	4.229243	0.001104	0.453488	0.001951	5.857021	0.001219	0.572237
0.002754	21.54435	0.002205	5.336699	0.001219	1.321941	0.003439	15.55676	0.003116	4.430621	0.001485	0.521401	0.002829	5.857021	0.001414	0.572237
0.003797	21.54435	0.002966	5.857021	0.00156	1.321941	0.004403	15.55676	0.004191	4.641589	0.001948	0.572237	0.003624	5.857021	0.001812	0.628029
0.005366	21.54435	0.003989	7.054802	0.001901	1.450829	0.005637	15.55676	0.005637	4.862602	0.002557	0.628029	0.005253	6.135907	0.002692	0.689261
0.007583	22.5702	0.005366	7.054802	0.002557	1.450829	0.007583	17.07353	0.007583	5.094138	0.003614	0.722081	0.007248	6.428073	0.003808	0.756463
0.002893	21.54435	0.007217	7.054802	0.003614	1.747528	0.010716	17.07353	0.010716	5.59081	0.005107	0.869749	0.010771	6.428073	0.005385	0.911163
0.010984	23.64489	0.010716	8.497534	0.004861	1.747528	0.015145	20.56512	0.015145	6.734151	0.007398	0.954548	0.016007	7.054802	0.007616	0.954548
0.015145	24.77076	0.015912	10.23531	0.006869	1.747528	0.021403	20.56512	0.022487	7.390722	0.010716	1.097499	0.022638	7.390722	0.011041	1.149757
0.021403	23.64489	0.023626	11.23324	0.010716	2.104904	0.030247	22.5702	0.031779	9.7701	0.015523	1.321941	0.032017	8.497534	0.016007	1.321941
0.033389	27.18588	0.033389	11.23324	0.015145	2.535364	0.047187	24.77076	0.047187	10.72267	0.021938	1.592283	0.047579	8.902151	0.023206	1.450829
0.010716	23.64489	0.049577	14.84968	0.021403	2.782559	0.070064	27.18588	0.070064	12.32847	0.033389	1.830738	0.068978	10.23531	0.033642	1.747528
0.049577	29.83647	0.073613	14.84968	0.031779	3.67838	0.099017	29.83647	0.104032	13.53048	0.049577	2.205131	0.1	11.23324	0.047579	2.009233
0.070064	32.74549	0.104032	19.63041	0.047187	4.862602	0.147022	35.93814	0.154469	16.29751	0.070064	2.782559	0.148608	13.53048	0.070707	2.535364
0.104032	37.64936	0.154469	23.64489	0.066686	4.862602	0.207777	43.28761	0.229359	19.63041	0.104032	3.511192	0.220844	15.55676	0.102507	2.915053
0.154469	41.32012	0.229359	25.95024	0.094243	6.428073	0.308511	47.5081	0.332246	23.64489	0.154469	4.430621	0.312337	17.07353	0.148608	3.351603
0.229359	47.5081	0.357806	34.30469	0.139934	7.742637	0.458083	52.14008	0.481286	27.18588	0.218301	5.59081	0.464159	20.56512	0.232055	4.037017
0.332246	54.62277	0.531278	45.34879	0.212974	8.902151	0.647379	62.80291	0.714623	34.30469	0.324138	7.054802	0.689779	24.77076	0.312337	4.862602
0.493325	62.80291	0.788852	54.62277	0.332246	11.23324	0.961242	83.02176	1.035193	41.32012	0.469541	8.902151	1.025068	28.48036	0.464159	6.428073
0.714623	79.24829	1.171304	65.79332	0.493325	14.17474	1.499566	91.11628	1.537076	49.77024	0.714623	11.23324	1.486083	34.30469	0.689779	7.742637
1.061087	91.11628	1.739175	79.24829	0.732499	18.73817	2.226586	120.4504	2.282281	62.80291	1.035193	14.84968	2.208442	41.32012	1.025068	10.23531
1.537076	109.7499	2.457865	95.45485	1.061087	23.64489	2.850596	145.0829	3.30608	79.24829	1.499566	17.8865	3.281928	49.77024	1.523336	12.32847
2.282281	132.1941	3.473542	126.1857	1.575524	28.48036	4.908933	166.8101	4.78914	100	2.17225	22.5702	4.757944	62.80291	2.154435	14.84968
3.388776	151.9911	4.908933	151.9911	2.226586	35.93814	6.93748	210.4904	7.111011	126.1857	3.30608	29.83647	7.070699	72.20809	3.364199	19.63041
0.324138	54.62277	7.288882	183.0738	3.30608	45.34879	10.30091	253.5364	10.55857	159.2283	4.78914	39.44206	10.77105	91.11628	4.999479	25.95024
4.908933	183.0738	10.30091	220.5131	4.78914	59.94843	14.92175	305.3856	15.295	200.9233	7.111011	52.14008	15.23336	114.9757	7.247948	31.25716
7.288882	220.5131	15.295	291.5053	6.603018	79.24829	21.61543	385.3529	22.15611	242.0128	10.30091	65.79332	22.08442	138.4886	10.50764	41.32012
10.82268	265.6088	21.61543	351.1192	10.30091	104.7616	32.89784	509.4138	32.09503	305.3856	15.295	83.02176	32.81928	183.0738	15.23336	52.14008
15.67758	319.9267	33.72073	422.9243	15.67758	138.4886	48.84737	613.5907	47.65534	403.7017	22.15611	109.7499	48.77217	220.5131	22.63803	65.79332
23.27838	422.9243	50.06922	559.081	22.71032	174.7528	70.75961	739.0722	70.75961	533.6699	32.09503	138.4886	70.70699	265.6088	33.64199	83.02176
33.72073	509.4138	70.75961	673.4151	32.89784	231.013	102.5014	932.6033	102.5014	705.4802	47.65534	191.791	102.5068	351.1192	49.99479	104.7616
50.06922	673.4151	105.0653	890.2151	47.65534	278.2559	152.1961	1176.812	152.1961	932.6033	69.03285	242.0128	156.1523	422.9243	72.47948	138.4886
72.52956	811.1308	148.482	1176.812	70.75961	351.1192	225.9838	1417.474	225.9838	1176.812	105.0653	319.9267	232.0552	559.081	107.7105	174.7528
107.6933	977.01	220.4691	1417.474	102.5014	443.0621	327.3569	1788.65	335.5452	1555.676	152.1961	422.9243	344.8533	739.0722	156.1523	220.5131
156.003	1232.847	311.5747	1873.817	156.003	559.081	462.6324	1963.041	486.066	2056.512	220.4691	585.7021	512.4806	977.01	232.0552	291.5053
231.6364	1555.676	486.066	2257.02	220.4691	739.0722	686.9259	2595.024	704.1083	2595.024	335.5452	739.0722	724.7948	1291.55	336.4199	403.7017
343.9384	1963.041	686.9259	3274.549	319.3683	932.6033					486.066	977.01			487.7217	533.6699
510.6867	2477.076			474.2045	1176.812					704.1083	1291.55			724.7948	705.4802
739.7734	2983.647			704.1083	1629.751
721.7206	3593.814

[marcocaggioni]

figure5 provides additional data

[marcocaggioni]

webplotdigitizer project

[marcocaggioni]

figure_6.csv

G_8pc		G_5pc		G_3pc		PG_8pc		PG_5pc		PG_3pc		P_8pc		P_5pc		P_3pc
X	Y	X	Y	X	Y	X	Y	X	Y	X	Y	X	Y	X	Y	X	Y
0.001455	268.7496	0.001421	156.9106	0.001421	60.61899	0.001603	268.4307	0.001529	150.3167	0.001603	43.15553	0.002134	236.8893	0.002185	91.20108	0.002134	29.45038
0.002229	282.5446	0.002177	160.8873	0.002177	61.38235	0.002394	282.3124	0.002338	160.0957	0.002284	43.70297	0.003045	249.0942	0.003269	92.35375	0.003118	30.96771
0.003257	297.0476	0.003257	167.0422	0.003181	64.53311	0.003492	289.5202	0.003575	168.3749	0.003492	46.54609	0.004554	261.9279	0.004775	94.70298	0.004775	32.15679
0.004759	316.2278	0.004873	173.4325	0.004759	66.16863	0.005093	300.6784	0.004745	177.0823	0.005215	49.57417	0.006653	278.9039	0.006976	97.11196	0.007143	32.56321
0.006791	332.4598	0.00712	182.3348	0.006953	68.69997	0.007429	312.2666	0.007255	186.24	0.007606	52.13787	0.009953	296.98	0.010436	97.11196	0.010436	33.39153
0.009921	362.8964	0.010403	191.6941	0.010159	70.44109	0.011094	324.3015	0.011094	195.8713	0.010583	54.83415	0.01454	312.2809	0.015245	99.58222	0.01561	34.24092
0.014496	391.1932	0.015199	204.0716	0.014843	72.22635	0.015804	349.7805	0.015436	206.0007	0.015436	59.14225	0.02124	336.723	0.022805	104.7129	0.021749	36.00507
0.021687	421.6965	0.022207	217.2484	0.022207	78.83864	0.023602	382.047	0.023602	219.4021	0.023602	62.98978	0.032535	363.0781	0.033315	111.4995	0.031773	37.86011
0.031685	460.3027	0.033223	234.1883	0.031685	83.92919	0.034426	417.29	0.034426	236.6397	0.033623	68.80044	0.046416	391.4959	0.048668	118.7259	0.046416	39.81072
0.046294	496.1948	0.048541	255.6282	0.046294	90.47357	0.051412	461.5658	0.050213	258.4692	0.050213	75.14713	0.069433	427.4734	0.071097	126.4207	0.071097	43.46922
0.067638	555.348	0.070921	275.5608	0.06926	98.75639	0.073241	523.574	0.074989	296.912	0.073241	81.05114	0.101431	460.9315	0.106353	136.3156	0.101431	46.87153
0.103619	621.5531	0.103619	304.576	0.101192	107.7975	0.109379	586.4732	0.11199	324.3015	0.109379	90.78816	0.151729	503.2899	0.159091	148.8426	0.151729	51.1789
0.147847	704.4109	0.151392	336.6464	0.147847	119.1481	0.15582	648.6998	0.163348	358.7109	0.15954	101.6949	0.221656	563.5197	0.226969	160.4924	0.221656	55.8821
0.216011	788.3864	0.226496	376.7792	0.216011	131.6938	0.227278	735.8484	0.238259	401.8043	0.232704	113.912	0.323808	615.3057	0.331571	177.4561	0.323808	63.36044
0.323172	882.3729	0.323172	421.6965	0.323172	147.3935	0.331506	813.9242	0.347523	450.0748	0.33942	129.2153	0.484379	697.648	0.484379	198.6927	0.484379	69.1831
0.472171	1000	0.483494	490.024	0.472171	173.4325	0.495076	911.7043	0.506895	497.8291	0.506895	146.5745	0.70761	771.3877	0.70761	231.013	0.724573	81.45338
0.689866	1133.308	0.72335	569.4227	0.70641	199.0275	0.705279	1047.305	0.757004	579.1269	0.739354	177.0823	1.058501	874.6175	1.083876	261.9279	1.058501	93.52099
1.032101	1316.938	1.032101	653.4576	1.032101	228.3998	1.078417	1218.334	1.130521	648.6998	1.104162	200.8721	1.583392	979.285	1.583392	296.98	1.583392	106.0363
1.544114	1511.29	1.544114	749.8942	1.507952	262.1068	1.572973	1399.54	1.648971	745.1827	1.610524	236.6397	2.313117	1082.793	2.368567	336.723	2.313117	121.746
2.256029	1734.325	2.203196	871.3997	2.256029	304.576	2.349101	1648.744	2.40518	866.8745	2.349101	275.284	3.379143	1212.373	3.460148	391.4959	3.379143	139.7831
3.296175	1990.275	3.296175	1000	3.296175	358.3834	3.426384	1966.96	3.508181	1034.186	3.346495	320.2392	5.054797	1374.617	5.17597	443.8873	4.93646	164.5749
4.815882	2493.097	4.931368	1176.663	4.815882	421.6965	4.997704	2259.512	5.239168	1203.073	5.117012	382.047	7.211485	1618.419	7.561376	509.6508	7.384358	193.7638
7.37776	2970.476	7.204983	1384.536	7.204983	490.024	7.463642	2628.5	7.463642	1399.54	7.28962	444.437	10.53498	1905.461	11.04612	592.5531	10.78752	231.013
10.52685	3628.964	10.77929	1649.648	10.52685	576.5933	10.88642	3135.815	11.4124	1628.092	11.14631	530.2157	15.75908	2187.762	16.13686	688.9407	15.75908	268.5907
16.12676	4489.251	15.38027	1941.08	15.38027	686.9997	15.87887	4753.432	16.64606	1917.992	16.25794	632.55	23.02183	2608.337	23.57371	831.7638	23.02183	320.2245
27.81339	5484.417	23.01024	2312.759	23.01024	839.2919			24.27984	2288.174	23.71374	764.2082	33.63171	2920.482	35.26347	991.6619	33.63171	391.4959
		34.42534	2790.308	33.61914	1000			35.41444	2661.843	34.58871	923.2695	52.74997	3481.915	51.51505	1152.97	50.30905	466.7571
		49.1193	3324.598	50.29719	1206.484			52.88843	3096.534	51.65528	1129.587	75.25636	4476.196	75.25636	1427.399	73.49455	563.5197
		75.24902	3815.239	75.24902	1473.935			77.14274	3836.557	77.14274	1364.698	109.9391	5270.092	112.5746	1789.482	107.3654	680.342
				109.9427	1823.348			115.2061	4519.699	112.5199	1712.287			160.6058	2419.003	160.6058	811.1308
				164.4839	2283.998					168.0389	1966.96					234.6229	967.0625
										282.3707	2661.843					350.968	1258.925
										442.0708	2661.843					525.0064	1539.121
										521.4505	3057.746
										600.7427	3382.183

[hippjb]

Looks great Marco!

[marcocaggioni]

these are possible figures, not sure if it is worth combining in a single figure or just keep two. keeping 2 for now since I'm using Manon's create_plot() function but did not figure how to make subplots.

in the HB mastercurve I added in gray the different terminal slope from the n of the HB fit

[marcocaggioni]

the notebook with the code to generate the figure is in the marco/figure from literature folder

https://github.com/ManonMarchand/three_component_model/blob/38a99a39b6019a1f70b0828d96913831f08874aa/marco/figure_from_literature/figure.ipynb