Mini Sector Shift (2 bytes): This field MUST be set to 0x0006. This field specifies the sector size of the Mini Stream as a power of 2. The sector size of the Mini Stream MUST be 64 bytes
Sector Shift (2 bytes): This field MUST be set to 0x0009, or 0x000c, depending on the Major Version field. This field specifies the sector size of the compound file as a power of 2
If Major Version is 3, the Sector Shift MUST be 0x0009, specifying a sector size of 512 bytes.
If Major Version is 4, the Sector Shift MUST be 0x000C, specifying a sector size of 4096 bytes
Mini Stream Cutoff Size (4 bytes): This integer field MUST be set to 0x00001000. This field specifies the maximum size of a user-defined data stream that is allocated from the mini FAT and mini stream, and that cutoff is 4,096 bytes. Any user-defined data stream that is greater than or equal to this cutoff size must be allocated as normal sectors from the FAT
Byte Order (2 bytes): This field MUST be set to 0xFFFE. This field is a byte order mark for all integer field specifying little-endian byte order.
From [MS-CFB]:
I don't think we validate this in this library