The documentation for broadcastEvent is in src/reference/interactive/protocol/protocol.rst, but doesn't seem to be in src/reference/interactive/protocol/protocol.pdf.
Update: It seems like it's changes 1.4.1 and 1.4.2 that aren't showing up in the pdf.
1.4.2 (2018-02-13)
Added world update and change methods.
1.4.1 (2017-10-20)
Added and documented global throtting.
Added the ability to fire one-off events to clients via ``broadcastEvent``.
The documentation for broadcastEvent is in src/reference/interactive/protocol/protocol.rst, but doesn't seem to be in src/reference/interactive/protocol/protocol.pdf.
Update: It seems like it's changes 1.4.1 and 1.4.2 that aren't showing up in the pdf.