Firefox Multi-Account Containers lets you keep parts of your online life separated into color-coded tabs that preserve your privacy. Cookies are separated by container, allowing you to use the web with multiple identities or accounts simultaneously.
This was an issue with Firefox and should have been fixed in a recent version. If you ecounter this issue again, please file a bug report on bugzilla.mozilla.org.
Also please make sure that:
Actual behavior
Opening an empty popup when I click on the Multi-Account Containers's icon
Expected behavior
Having some settings when I click on Multi-Account Containers's icon
Steps to reproduce
Notes