For more details, please refer to W5100S-EVB page in WIZnet Docs page.
WIZnet W5100S Hardwired TCP/IP chip
STMicroelectronics STM32F103VCT6 MCU
Pin-compatible with Arduino Shields designed for the UNO Rev3
2 x Push button switch(SW), 1 x RGB LED
1-Channel 10/100Mbps Ethernet Connector (RJ-45 with transformer) – (If you want to RJ-45, Contact us)
Micro USB B connector and 5-pin(2.54mm) Cortex debug connector for SWD(Serial Wire Debug)
W5100S-EVB Arduino Compatible Pinout
W5100S-EVB External Pinout(left)
W5100S-EVB External Pinout(Right)
These are libraries source code and example projects based on STM32CubeIDE If you want to base on TrueStudio or Ecplipse, change git branch master to truestudio_ver
The tree of Directory is below.
W5100S-EVB
┣ FSMC_DMA or SPI_DMA
┣ Core
┃ ┣ Inc
┃ ┃ ┗ main.h
┃ ┣ Src
┃ ┃ ┗ main.c
┃ ┗ Startup
┗ Drivers
┣ CMSIS
┣ STM32F1xx_HAL_Driver
┗ ioLibrary_Driver
┣ Application
┣ Ethernet
┗ Internet
Various materials are could be found at W5100S-EVB page in WIZnet Docs. And refer to this link W5100S Hardware data